Oxo-titanium and -zirconium diphosphines [(η-C5H5)2M(CH2PPh2]2O (with M = Ti,Az) as building blocks for heterobimetallic complexes |
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| Authors: | Francois Senocq Mario Basso-Bert Robert Choukroun Daniele Gervais |
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| Affiliation: | Laboratoire de Chimie de Coordination du CNRS, Unité 8241 liée par convention à l''Université Paul Sabatier, 205 route de Narbonne, 31400 Toulouse France |
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| Abstract: | Oxo-titanium and -zirconium diphosphines [(η-C5H5)2M(CH2PPh2)]2 (with M = Ti, Zr) were synthesized and treated with [Rh(CO)2Cl]2 to give the heterobimetallic d0-d8 species O[(η-C5H5)2M(CH2PPh2)]2Rh(CO)Cl. |
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