Transition metal derivatives of arenediazonium ions: XIV. Reactions of arenediazomolybdenum(II) complexes with neutral and anionic Lewis bases |
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Authors: | FJ Lalor DM Condon |
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Institution: | Department of Chemistry, University College, Cork Ireland |
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Abstract: | The reactions of arenediazomolybdenum(II) complexes such as (η-C5H5)Mo(N2C6H4CH3-p)I2]2, (η-C5H5)Mo(CO species with neutral and anionic monodentate or chelating ligands have been investigated. The new arenediazo complexes isolated from these reactions include neutral species such as (η-C5H5)Mo(PPh3)(N2C6H4CH3-p)I2 and (η-C5H5)Mo(N2C6H4CH3-p) cations of the type η-C5H5)Mo(bipy)(N2C6H4CH3-p)I]+ and the anion (η-C5H5)Mo(N2C6H4CH3-p)I3]?. The structures of the new complexes are discussed. |
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