Phosphaalkynes as ligands in organometallic chemistry. Syntheses and 31p NMR spectra of platinum(II), palladium(II) and rhodium(I) complexes of dη5-cyclopentadienyltetracarbonyl-μ-(3,3-dimethyl-1-phosphabutyne)dimolybdenum, [Mo2(CO)4(η-c5H5)2tBuCP)] |
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| Authors: | Mohamed F Meidine Catherine J Meir Stephen Morton John F Nixon |
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| Institution: | School of Chemistry and Molecular Scienes, University of Sussex, Brighton BNI OQJ Great Britain |
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| Abstract: | Syntheses of the complexes trans-PtCl2(PR3)Mo2(CO)4(η5-C5H5)2(tBuCP)], (PR3=PEt3, PPr3, PBu3, PPh2Me, PPhMe2) trans-PdCl2(PBu3)Mo2(CO)4(η5-C5H5)2(tBuCP)], and transRhCl{(PF2NMe)2CO}Mo2(CO)4(η5-C5H5)2(tBuCP)] are described and their 31P NMR spectra presented and discussed. |
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