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Spectroscopic properties, energy transfer and structural analysis of Sr2CeO4:M+ and Sr2CeO4:Eu3+, M+ (M+ = Li+, Na+, K+)
Authors:Shi Li-Li  Li Cheng-Yu  Su Qiang
Institution:(1) State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, People’s Republic of China;
Abstract:The room-temperature luminescent emission characteristics of Sr2CeO4:M+ and Sr2CeO4:Eu3+,M+ (M+ = Li+, Na+, K+) have been investigated under UV excitation. By introducing appropriate alkali metal cations dopants (Li+, Na+, K+) into the crystalline lattice, not only emission color of the blue-white-emitting Sr2CeO4 doped with low Eu3+ content can be tuned to green, but also the red emission intensity of Sr2CeO4 doped with high Eu3+ concentration is strengthened significantly. The relevant mechanisms have been elucidated in detail.
Keywords:
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