Synthesis, structure and photoluminescence of [Cu(acac)(dppe)]n with novel 1D zigzag chain-like motif |
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| Authors: | Y-M Xie J-H Wu |
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| Institution: | 1. The Key Laboratory for Functional Materials of Fujian Higher Education, College of Materials Science and Engineering, Huaqiao University, Quanzhou, Fujian, 362021, P.R. China
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| Abstract: | A novel complex Cu(acac)(dppe)]n (1) acac = acetylacetone; dppe = 1,2-bis(diphenylphosphino)ethane] was obtained by solution reactions and structurally characterized by X-ray diffraction. The crystal structure analysis indicates that the title complex is characteristic of a polymeric chain formed by the dppe ligands bridging neighboring copper centers. The copper atom is in a distorted tetrahedral geometry. Photoluminescent investigation reveals that the title complex displays a strong emission in bluelight region. |
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