Practical reduction of imines by NaBH4/alumina under solvent-free conditions: An efficient route to secondary amine |
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作者姓名: | Foad Kazemi Ali Reza Kiasat Ebrahim Sarvestani |
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作者单位: | a Institute for Advanced Studies in Basic Sciences(IASBS), Zanjan 45195, Iran;b Chemistry Department, College of Science, Shahid Chamran University, Ahvaz 61357-4-3169, Iran |
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基金项目: | Partial support for this work by Chamran University Research Council are gratefully acknowledged. |
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摘 要: | Sodium borohydride supported on alumina reduces imines to the corresponding secondary amines in high to excellent isolated yields under solvent-free conditions. Noteworthy is that highly chemoselective reactions were achieved in the presence of other functional groups such as halogen, nitro, and cyano groups.
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关 键 词: | 亚胺 次级胺 溶剂 氢硼化钠 |
收稿时间: | 2008-03-27 |
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