Investigation of the usefulness of NTA, EDTA and DTPA in separation of some platinum metals on cellulose exchangers |
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Authors: | Brajter K Słonawska K |
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Institution: | Department of Chemistry, Warsaw University, Warsaw, Poland. |
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Abstract: | The possibility of using NTA, EDTA and DTPA as complexing agents for separation of some platinum group ions on cellulose ion-exchangers has been investigated. The greatest differences in the affinities of Pd(II) and Pt(IV) toward the cellulose ion-exchangers are obtained in the presence of DPTA, Cellex D (as ion-exchanger) in hydroxide form. The column separation of Pd(II) from Pt(IV), Rh(III) from Pd(II) and of a Rh(III)Pd(II)Pt(IV) mixture can be achieved with DPTA and chloride solutions. The method can be for determination of the components of RhPdPt alloys. |
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