Synthesis of the first stable carborane containing simple enol |
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| Authors: | L. I. Zakharkin V. A. Ol'shevskaya G. G. Zhigareva |
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| Affiliation: | (1) A. N. Nesmeyanov Institute of Organoelenrent Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation |
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| Abstract: | A carborane-containing stable simple enol — 1-2-isopropyl-o-carboran-I-yl)-1-phenyl2-mesityl-2-lrydroxyctlrylcne — has been synthesized. This enol does not isomerize to the starting ketone or keto-enol mixture even after prolonged heating in benzene in the presence of CF3COOH.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1561–1563, June, 1996. |
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| Keywords: | carborane-containing ketones and enols synthesis isoncrization |
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