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| Electron－rich Polynuclear Transition Metal Clusters：Ⅰ． The Clusters with Chalcogen Bridges and Phosphine Ligands | |
| 引用本文： | Hong Mao-Chun,Jiang Fei-Long ,Kang Bei-Sheng,Cao Rong Huang,Zhi-Ying,Liu Han-Qin(State Key Laboratory of Structural Chemistry,and Fujian Institute ofResearch on the Structure of Matter,Academia Sinica.Fuzhou,350002). Electron－rich Polynuclear Transition Metal Clusters：Ⅰ． The Clusters with Chalcogen Bridges and Phosphine Ligands[J]. 结构化学, 1994, 0(2) |
| 作者姓名： | Hong Mao-Chun Jiang Fei-Long Kang Bei-Sheng Cao Rong Huang Zhi-Ying Liu Han-Qin(State Key Laboratory of Structural Chemistry and Fujian Institute ofResearch on the Structure of Matter Academia Sinica.Fuzhou 350002) |
| 作者单位： | State Key Laboratory of Structural Chemistry，and Fujian Institute ofResearch on the Structure of Matter，Academia Sinica.Fuzhou，350002 |
| 摘 要： | Ｅｌｅｃｔｒｏｎ－ｒｉｃｈＰｏｌｙｎｕｃｌｅａｒＴｒａｎｓｉｔｉｏｎＭｅｔａｌＣｌｕｓｔｅｒｓ：Ⅰ．ＴｈｅＣｌｕｓｔｅｒｓｗｉｔｈＣｈａｌｃｏｇｅｎＢｒｉｄｇｅｓａｎｄＰｈｏｓｐｈｉｎｅＬｉｇａｎｄｓＨｏｎｇＭａｏ－Ｃｈｕｎ；ＪｉａｎｇＦｅｉ－Ｌｏｎ... |
Electron-rich Polynuclear Transition Metal Clusters:Ⅰ.The Clusters with Chalcogen Bridges and Phosphine Ligands |
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| Hong Mao-Chun,Jiang Fei-Long ,Kang Bei-Sheng,Cao Rong Huang,Zhi-Ying,Liu Han-Qin. Electron-rich Polynuclear Transition Metal Clusters:Ⅰ.The Clusters with Chalcogen Bridges and Phosphine Ligands[J]. Chinese Journal of Structural Chemistry, 1994, 0(2) | |
| Authors: | Hong Mao-Chun Jiang Fei-Long Kang Bei-Sheng Cao Rong Huang Zhi-Ying Liu Han-Qin |
| Abstract: | This paper presents a versatile method for synthesizing electron-rich polynuclear transition metal clusters with chalcogen bridges and phosphine ligands.The reactions of transition metal complexes(R3P)2MX2(M=Co,Ni;R=Ph,Bu,Et;X=Cl,Br) with bridging reagents Na2Ex (E=S,Se;x=1.2) are described.The geometric and electronic structures of a series of polynuclear transition metal clusters with trianglar M3 units are also discussed. |
| Keywords: | polynuclear transition metal clusters chalcogen bridges triangular M_3 unit synergistic effect |
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