Characterization of MoO3 nanobelt cathode for Li-battery applications |
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Authors: | C.V. Subba Reddy Z.R. Deng Q.Y. Zhu Y. Dai J. Zhou W. Chen S.-I. Mho |
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Affiliation: | (1) School of Materials Science and Engineering, Wuhan University of Technology, Wuhan, 430070, P.R. China;(2) Division of Energy Systems Research, Ajou University, Suwon, 443-749, Korea |
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Abstract: | Molybdenum trioxide (MoO3) and PPyxMoO3 (x=0.5 and 1) nanobelts were obtained by the simple hydrothermal process from MoO3 sol. The morphology and structure of the samples were characterized using X-ray diffractometry (XRD), Fourier transformation infrared spectroscopy (FTIR), Raman spectra, SEM and AFM. The results show that the H atoms in polypyrrole are H-bonded with the O atoms in the Mo=O bonds of MoO3 nanobelts. Using the electrolyte, we fabricated electrochemical cells with a configuration of Li/(LiPF6+EC+DMC)/(MoO3+acetyleneblack+PTFE) and studied discharge profiles. PACS 81.07.BC; 81.05.Je; 82.47.Aa; 82.45.Fk; 82.45.Gj |
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