Structural phase transformations and physical properties of intercalation compounds in the Cr0.5Ti(Se1−x Tex)2 system

The atomic structure and magnetic and electric properties of the Cr_0.5TiSe₂-Cr_0.5TiTe₂ system of intercalated phases were studied in detail by gradually replacing selenium by tellurium. It was revealed that this replacement changes the crystalline structure from monoclinic in the initial compounds to hexagonal in the compounds containing various types of chalcogen atoms; this is accompanied by disordering of chromium atoms in the van der Waals gaps. The electrical resistance and magnetic characteristics vary nonmonotonically on replacement of selenium by tellurium, which is associated with a change in the degree of atomic disordering during the transition from Cr_0.5TiSe₂ to Cr_0.5TiTe₂.