| Synthesis and Crystallographic Characterization of Complex [(CH_3)_3NCH_2CH_2N(CH_3)_3][HgI_4]·H_2O Containing Novel Cation |
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| 引用本文： | CHEN Yong LI Hao-Hong CHEN Zhi-Rong②,HUANG Chang-Cang REN Yong-Gang CHEN Jia-Hong.Synthesis and Crystallographic Characterization of Complex [(CH_3)_3NCH_2CH_2N(CH_3)_3][HgI_4]·H_2O Containing Novel Cation[J].结构化学,2004(12). |
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| 作者姓名： | CHEN Yong LI Hao-Hong CHEN Zhi-Rong② HUANG Chang-Cang REN Yong-Gang CHEN Jia-Hong |
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| 作者单位： | Department of Chemistry，Fuzhou University，Fuzhou，Fujian 350002，China |
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| 基金项目： | This work was supported by the Foundation of Education Committee of Fujian Province (JB01020) |
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| 摘 要： | 1 INTRODUCTION The crystal structures of several tetrahalogeno-mercurates (II) have been reported with a wide va-riety of stereochemical arrangements1, . These stu- 2]dies have shown that the Hg atom…
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Synthesis and Crystallographic Characterization of Complex [(CH_3)_3NCH_2CH_2N(CH_3)_3][HgI_4]·H_2O Containing Novel Cation |
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| Abstract: | The title compound has been synthesized by the reaction of HgI2 and (CH3)3- NCH2CH2N(CH3)3]I2 with pH = 7.5 at room temperature, and its crystal structure was determined by single-crystal X-ray diffraction analysis. The title compound crystallizes in monoclinic system, space group P21/c with a = 8.3075(8), b =15.8084(19), c =15.390(2) ?, β = 95.192(4)o, V = 2012.9(4) ?3, Z = 2, Dc = 2.824 g/cm3, F(000) = 1502, C14H39N4O2Hg2I8, Mr = 1711.87, μ(MoKα) = 13.768 mm-1, the final R = 0.0465 and wR = 0.1293 for 3046 observed reflections with I > 2σ (I). The title compound consists of cations (C8H22N2]2+) and anion (HgI4 ), which are combined by static 2- attracting forces to form the so-called organic-inorganic hybrid material. |
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| Keywords: | metal iodide template synthesis hybrid material quaternary ammonium |
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