| 肟的无污染氧化 |
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| 引用本文： | 张青枝,张深松,刘新铭,张金明.肟的无污染氧化[J].应用化学,2001,18(4):299-0. |
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| 作者姓名： | 张青枝 张深松 刘新铭 张金明 |
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| 作者单位： | 河南师范大学 |
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| 基金项目： | 国家自然科学基金资助项目(29477266) |
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| 摘 要： | No2;污染治理;二噁烷;肟的无污染氧化
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| 关 键 词： | No2 污染治理 二噁烷 肟的无污染氧化 |
| 文章编号： | 1000-0518(2001)04-0299-03 |
| 收稿时间： | 2009-06-29 |
| 修稿时间： | 2000年9月12日 |
Pollution-free Oxidation
of Oximes |
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| ZHANG Qing-zhi,ZHANG Shen-Song,LIU Xin-ming,ZHANG Jin-ming.Pollution-free Oxidation
of Oximes[J].Chinese Journal of Applied Chemistry,2001,18(4):299-0. |
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| Authors: | ZHANG Qing-zhi ZHANG Shen-Song LIU Xin-ming ZHANG Jin-ming |
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| Institution: | ZHANG Qing Zhi *,ZHANG Shen Song,LIU Xin Ming,ZHANG Jin Ming |
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| Abstract: | The liquid dioxane-NO2 additive was prepared by absorption of NO2 gas into dioxane. Theexperimental results showed that the additive could convert oximes (13 oxime derivatives were test-ed.) to corresponding ketones at room temperature for 2～4. 5 hours, while the NO2 as an original ox-idant was reduced to N2. At molar ratio of oxime to dioxane-NO2 = 4 : 1 the maximum yields of hydra-zone derivatives as a result of reaction with 2,4-dinitrophenylhydrazine could be obtained. The processprovides a pollution-free method for treatment of waste NO2 gas and selective degradation of oximes. |
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| Keywords: | NO 2 pollution treatment dioxane oxime |
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