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Cu‐catalyzed coupling of arylsulfinic salts with arylsilanes under mild conditions
Authors:Xiaomin Yang  Yanyan Cao  Enbo Li  Pengmei Zhang  Zhanzhong Hou
Affiliation:1. Department of Chemistry, College of Science, Hebei North University, Zhangjiakou, China;2. College of Information Science and Engineering, Hebei North University, Zhangjiakou, China
Abstract:
Arylsilanes were efficiently coupled with arylsulfinic salts for the first time under mild conditions. Diarylsulfone derivatives were easily synthesized in high yields with the assistance of nitrogen‐containing ligands and KF. The transformation is simple and efficient and the starting materials are readily available. Copyright © 2014 John Wiley & Sons, Ltd.
Keywords:arylsilanes  sodium arylsulfinate  cross‐coupling  diarylsulfone synthesis
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