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The first selective one-pot synthesis of 1,3-dicarbonyl adamantanes from adamantane and 1,3-dimethyladamantane |
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| Authors: | Irena S Akhrem Dzhul’etta V AvetisyanLuidmila V Afanas’eva |
| Institution: | A.N. Nesmeyanov Institute of Organoelement Compounds Russian Academy of Sciences, 28 Vavilov Street, 119991 Moscow, Russian Federation |
| Abstract: | A new approach to a simple one-pot functionalization of adamantane and 1,3-dimethyladamantane with CO and various nucleophiles in the presence of the superelectrophilic complex, CBr4·2AlBr3 provides access to important 1,3-dicarbonyl adamantanes with two new functional groups at the bridge-head positions. |
| Keywords: | One-pot synthesis sp3 C-H bifunctionalization of adamantanes Superelectrophiles 1 3-Dicarbonyl adamantanes |
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