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First stereoselective total synthesis of panaxjapyne C |
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| Authors: | Pallavi ThakurB. Kumaraswamy G. Raji ReddyRakeshwar Bandichhor K. Mukkanti |
| Affiliation: | a Maithili Life Sciences Pvt. Ltd., Plot No.146 A, Phase-II, IDA, Mallapur, Hyderabad 500 076, India b Innovation Plaza, IPD, R&D, Dr. Reddy’s Laboratories Ltd., Survey Nos. 42, 45,46, and 54, Bachupally, Qutubullapur, R.R. District 500 073, Andhra Pradesh, India c Institute of Science and Technology, Center for Environmental Science, JNT University, Kukatpally, Hyderabad 500 072, India |
| Abstract: | The first stereoselective total synthesis of polyacetylene panaxjapyne C is described. The key reactions include regioselective opening of the epoxide and Cadiot-Chodkiewicz cross-coupling reactions. l-Ascorbic acid was used as a chiral pool material for the construction of the both terminal acetylenes. |
| Keywords: | Polyacetylene Araliaceae Regioselective opening of epoxide Cadiot-Chodkiewicz cross coupling smallcaps" >l-ascorbic acid |
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