Novel supramolecular architectures in group 13 perfluoroaryl complexes. Synthesis and structures of [AlMe(C6F5)(mu-Me)]2 and GaMe(C6F5)2 |
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Authors: | Hair Gregory S Cowley Alan H Gorden John D Jones Jamie N Jones Richard A Macdonald Charles L B |
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Affiliation: | The University of Texas at Austin, Chem. & Biochem. Dept., 1 University Station A5300, Austin, Texas 78712-0165, USA. |
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Abstract: | Novel supramolecular architectures are observed in the solid state structures of [AlMe(C6F5)(mu-Me)]2 (1) and Ga(C6F5)2Me (2) via pi-pi stacking between C6F5 rings and intermolecular aryl-F-->Ga interactions, respectively. |
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