Preparation,structure, and some coordination properties of 2-chloro-3,3-diphenyl-3-thioxo-1-(2,4,6-tri-t-butylphenyl)-1,3-diphosphapropene |
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| Authors: | Ito Shigekazu Liang Hongze Yoshifuji Masaaki |
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| Affiliation: | Department of Chemistry, Graduate School of Science, Tohoku University, Aoba, Sendai 980-8578, Japan. |
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| Abstract: | ![]()
A sterically encumbered 3-thioxo-1,3-diphosphapropene, bearing a P=C-P=S skeleton, was prepared, characterised, and allowed to react with a carbonyltungsten(0) reagent and iodine affording the corresponding chelate tungsten(0) complex and charge-transfer complex with iodine, respectively, which were analysed by the X-ray crystallography. |
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