| 1,5-二硝基-2,4-二硝亚胺基-六氢化-1,3,5-三嗪的合成与表征 |
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| 引用本文： | 李建康,周诚,杨威,王友兵,王伯周.1,5-二硝基-2,4-二硝亚胺基-六氢化-1,3,5-三嗪的合成与表征[J].光谱实验室,2012,29(4):2540-2542. |
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| 作者姓名： | 李建康 周诚 杨威 王友兵 王伯周 |
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| 作者单位： | 西安近代化学研究所一部 西安市雁塔区丈八东路168号一部 710065 |
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| 摘 要： | 以硝基胍和甲醛为原料,在盐酸中反应得到亚甲基二硝基胍,经HNO3/Ac2O硝化得到1,5-二硝基-2,4-二硝亚胺基-六氢化-1,3,5-三嗪,产率为71.4%,并采用核磁共振光谱、红外光谱、质谱以及元素分析等进行了结构表征,研究了硝化剂、反应温度和反应时间等条件对硝化反应的影响。
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| 关 键 词： | 1 5-二硝基-2 4-二硝亚胺基-六氢化-1 3 5-三嗪 合成 表征 |
Synthesis and Characterization of 2,4-Dinitrimino - 1,5-Dinitrohexahydro- 1,3,5-Triazine |
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| LI Jian-Kang
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ZHOU Cheng
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YANG Wei
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WANG You-Bing
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WANG Bo-Zhou.Synthesis and Characterization of 2,4-Dinitrimino - 1,5-Dinitrohexahydro- 1,3,5-Triazine[J].Chinese Journal of Spectroscopy Laboratory,2012,29(4):2540-2542. |
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| Authors: | LI Jian-Kang ZHOU Cheng YANG Wei WANG You-Bing WANG Bo-Zhou |
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| Institution: | LI Jian-Kang Zhou Cheng Yang Wei Wang You-Bing Wang Bo-Zhou (No.1 Department of Xi’an Modern Chemistry Research Institute,Xi’an 710065,P.R.China) |
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| Abstract: | Bis（nitroguanidine） methane was prepared by nitroguanidine and formaldehyde as raw materials in hydrochloric acid,and 2,4-dinitrimino-1,5-dinitrohexahydro-l,3,5-triazine was synthesized by the nitration with HNO3/AC2O with the yield of 71.4%.The structure of 2,4- dinitrimino-1,5-dinitrohexahydro-l,3,5-triazine was characterized by 1H NMR,13C NMR,FTIR and elemental analysis.The influences of nitrating agent,reaction time and temperature on nitration reaction were investigated. |
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| Keywords: | 2 4-Dinitrimino-1 5-Dinitrohexahydro-1 3 5-Triazine Synthesis Characterization |
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