| 1-二茂铁乙基膦酸的合成与表征 |
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| 引用本文： | 王宇飞,王利平,张粉云.1-二茂铁乙基膦酸的合成与表征[J].光谱实验室,2012,29(3):1710-1712. |
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| 作者姓名： | 王宇飞 王利平 张粉云 |
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| 作者单位： | 1. 中州大学化工食品学院 郑州市英才街6号 450044
2. 中国铝业中州分公司技术中心 河南省焦作市马村区 454171 |
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| 摘 要： | 以1-二茂铁乙醇为原料,与三氯化磷反应后加入乙醇酯化,经Michaelis-Arbuzov重排合成1-二茂铁乙基膦酸二乙酯,再通过Me3SiBr-Et3N体系水解制得1-二茂铁乙基膦酸。利用IR、NMR、MS等实验手段对目标产物进行了表征,结果表明与预期结构相符。以1-二茂铁乙醇计算,总收率为35%。
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| 关 键 词： | 1-二茂铁乙醇 膦酸 重排 |
Synthesis and Characterization of 1-Ferrocenyl Ethyl Phosphonic Acid |
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| WANG Yu-Fei
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WANG Li-Ping
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ZHANG Fen-Yun.Synthesis and Characterization of 1-Ferrocenyl Ethyl Phosphonic Acid[J].Chinese Journal of Spectroscopy Laboratory,2012,29(3):1710-1712. |
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| Authors: | WANG Yu-Fei WANG Li-Ping ZHANG Fen-Yun |
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| Institution: | WANG Yu-Fei WANG Li-Ping ZHANG Fen-Yun a(College of Chemical Engineering and Food,Zhongzhou University Zhengzhou 450044,P.R.China)a(Center of Technology,Aluminum Corporation of China Limited Zhongzhou Branch,Jiaozuo,Henan 454171,P.R.China) |
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| Abstract: | 1-Ferrocenyl ethyl phosphonate diethyl ester was synthesized with 1-ferrocenyl ethanol as raw material by reaction of with phosphorus trichloride,then was alcoholysis and rearrangement.Subsequently,the product was hydrolyzed to prepare 1-ferrocenyl ethyl phosphonic acid by Me3SiBr-Et3N system.The compound was characterized by IR,NMR and MS,and the results showed that the structure was the same as expectation.The overall yield was 35% with calculation of 1-ferrocenyl ethanol. |
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| Keywords: | 1-Ferrocenyl Ethanol Phosphonic Acid Rearrangement |
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