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Few-layer graphene growth from polystyrene as solid carbon source utilizing simple APCVD method
Institution:1. College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun 113001, PR China;2. School of New Energy, Shenyang Institute of Engineering, Shenyang 110136, PR China;3. College of Petroleum Engineering, Liaoning Shihua University, Fushun 113001, PR China;1. School of Physical Electronics, Joint Laboratory for Police Equipment Research, University of Electronic Science and Technology of China, Chengdu 610054, PR China;2. School of Physics and Mech-tronic Engineering, Sichuan University of Arts and Science, Dazhou 635000, PR China;1. Department of Physics and Astronomy, University of Manitoba, Winnipeg, Canada R3T 2N2;2. Department of Physics/Theoretical Physics, University of Oulu, Oulu FIN-90014, Finland;2. School of Electrical Engineering, University of Belgrade, Bulevar kralja Aleksandra 73, 11120 Belgrade, Serbia;3. Institute of Microwaves and Photonics, School of Electronic and Electrical Engineering, University of Leeds, Woodhouse Lane, Leeds LS2 9JT, UK
Abstract:This research article presents development of an economical, simple, immune and environment friendly process to grow few-layer graphene by controlling evaporation rate of polystyrene on copper foil as catalyst and substrate utilizing atmospheric pressure chemical vapor deposition (APCVD) method. Evaporation rate of polystyrene depends on molecular structure, amount of used material and temperature. We have found controlling rate of evaporation of polystyrene by controlling the source temperature is easier than controlling the material weight. Atomic force microscopy (AFM) as well as Raman Spectroscopy has been used for characterization of the layers. The frequency of G′ to G band ratio intensity in some samples varied between 0.8 and 1.6 corresponding to few-layer graphene. Topography characterization by atomic force microscopy confirmed Raman results.
Keywords:APCVD  Polystyrene  Solid carbon source  Graphene  Raman spectroscopy  AFM
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