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Self-assembly of bidentate ligands for combinatorial homogeneous catalysis: asymmetric rhodium-catalyzed hydrogenation
Authors:Weis Martine  Waloch Christoph  Seiche Wolfgang  Breit Bernhard
Affiliation:Institut für Organische Chemie und Biochemie, Albert-Ludwigs-Universit?t Freiburg, Germany.
Abstract:The first chiral ligand library based on self-assembly through complementary hydrogen-bonding was realized. From a 10 x 4 ligand library, catalysts that show excellent activity and enantioselectivity for the asymmetric rhodium-catalyzed hydrogenation have been identified.
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