Self-assembly of bidentate ligands for combinatorial homogeneous catalysis: asymmetric rhodium-catalyzed hydrogenation |
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Authors: | Weis Martine Waloch Christoph Seiche Wolfgang Breit Bernhard |
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Affiliation: | Institut für Organische Chemie und Biochemie, Albert-Ludwigs-Universit?t Freiburg, Germany. |
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Abstract: | The first chiral ligand library based on self-assembly through complementary hydrogen-bonding was realized. From a 10 x 4 ligand library, catalysts that show excellent activity and enantioselectivity for the asymmetric rhodium-catalyzed hydrogenation have been identified. |
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