Sulfonated N-heterocyclic carbenes for Suzuki coupling in water |
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| Authors: | Fleckenstein Christoph Roy Sutapa Leuthäusser Steffen Plenio Herbert |
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| Affiliation: | Anorganische Chemie im Zintl-Institut, Petersenstr. 18, 64287 Darmstadt, Germany. |
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| Abstract: | ![]()
Sulfonated, water-soluble imidazolium and imidazolinium salts were synthesized and the respective Pd-complexes with N,N'-bis(2,6-dialkyl-4-SO(3)(-)-phenyl)imidazol-2-ylidene and N,N'-bis(2,6-dialkyl-4-SO(3)(-)-phenyl)-4,5-dihydroimidazol-2-ylidene ligands were applied in aqueous Suzuki coupling reactions of aryl chlorides. |
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