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Preparation and Characterization of Electrodes Modified with Pyrrole Surfactant,Multiwalled Carbon Nanotubes and Metallophthalocyanines for the Electrochemical Detection of Thiols |
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| Authors: | Magdalena Rangel Argote Elizabeth Sánchez Guillén Ana Gabriela Gutiérrez Porras Oracio Serrano Torres Cyrille Richard José H. Zagal Fethi Bedioui Silvia Gutierrez Granados Sophie Griveau |
| Affiliation: | 1. Department of Chemistry, Division of Natural Sciences, University of Guanajuato, Guanajuato Campus, Guanajuato, Mexico;2. Chimie ParisTech, Ecole Nationale Supérieure de Chimie de Paris, Unité de Technologies Chimiques et Biologiques pour la Santé, Paris, France;3. CNRS, Unité de Technologies Chimiques et Biologiques pour la Santé, UMR 8258, Paris, France;4. Université Paris Descartes, Sorbonne Paris Cité, Unité de Technologies Chimiques et Biologiques pour la Santé, Paris, France;5. INSERM, Unité de Technologies Chimiques et Biologiques pour la Santé (N°?1022), Paris, France;6. Departamento de Quimica de los Materiales, Facultad de Quimica y Biologia Universidad de Santiago de Chile, Casilla 40, Correo 33, Santiago, Chile |
| Abstract: | Our aim was to prepare hybrid electrodes active towards the electrooxidation of thiols by the co‐immobilization of native carbon nanotubes (CNTs) and cobalt phthalocyanine (CoPc) from aqueous solutions. This strategy was adopted to avoid the oxidation of CNTs that can induce a modification of their exceptional properties. To do so, a hydrosoluble pyrrole surfactant was used to get homogeneous aqueous dispersions of CNTs and CoPc and to trap both materials on the electrode via the electropolymerization of the pyrrole surfactant. The hybrid electrodes exhibit a good electrocatalytic activity towards the oxidation of L ‐cysteine and glutathione. Their performances in terms of limit of detection (0.01 mM) are compatible with the detection of these thiols in biological samples. |
| Keywords: | Hybrid electrodes Carbon nanotubes Cobalt phthalocyanine Pyrrole surfactant Electrocatalysis |