New routes to high nuclearity clusters: fluoride-based octametallic and tridecametallic clusters of manganese |
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| Authors: | Jones Leigh F Brechin Euan K Collison David Raftery James Teat Simon J |
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| Institution: | Department of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK. |
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| Abstract: | The reaction of MnF(3) with 5,6-dimethylbenzotriazole (Me(2)BTAH) gives the Mn(III)(8)] complex Mn(8)O(4)(OMe)(2)(Me(2)BTA)(6)F(8)(Me(2)BTAH)(MeOH)(8)] and the Mn(IV)(3)Mn(III)(10)] complex Mn(13)O(12)(Me(2)BTA)(12)F(6)(MeOH)(10)(H(2)O)(2)]. The octametallic species is an "intermediate" in the formation of the tridecametallic cluster. |
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