Oxidations of two-dimensional semiconductors: Fundamentals and applications |
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Authors: | Junqiang Yang Xiaochi Liu Qianli Dong Yaqi Shen Yuchuan Pan Zhongwang Wang Kui Tang Xianfu Dai Rongqi Wu Yuanyuan Jin Wei Zhou Song Liu Jian Sun |
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Institution: | 1. School of Physics and Electronics, Central South University, Changsha 410083, China;2. State Key Laboratory of Chemical Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Institute of Chemical Biology and Nanomedicine (ICBN), Hunan University, Changsha 410082, China |
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Abstract: | Since the discovery of graphene, two-dimensional (2D) semiconductors have been attracted intensive interest due to their unique properties. They have exhibited potential applications in next generation electronic and optoelectronic devices. However, most of the 2D semiconductor are known to suffer from the ambient oxidation which degrade the materials and therefore hinder us from the intrinsic materials’ properties and the optimized performance of devices. In this review, we summarize the recent progress on both fundamentals and applications of the oxidations of 2D semiconductors. We begin with the oxidation mechanisms in black phosphorus, transition metal dichalcogenides and transition metal monochalcogenides considering the factors such as oxygen, water, and light. Then we show the commonly employed passivation techniques. In the end, the emerging applications utilizing controlled oxidations will be introduced. |
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