Synthesis,crystal structure,and third-order nonlinear optical properties of a copper(I) one-dimensional coordination polymer |
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| Authors: | Y Li Z X Zhang T Li K C Li |
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| Institution: | 1.College of Science,Guangdong Ocean University,Zhanjiang,P.R. China;2.College of Chemical Engineering and Light Industry,Guangdong University of Technology,Guangzhou,P.R. China;3.College of Chemistry,Jilin University,Changchun,P.R. China |
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| Abstract: | A copper(I) thiocyanate coordination polymer Cu(Phen)(μ-NCS)]n (I) (Phen = 1,10-phenan-throline) has been synthesized by the low-temperature solid-state reaction. Single-crystal X-ray analyses
reveal that compound I possesses a type of one-dimensional (1D) framework structure. Polymer I was characterized by elemental analyses, IR spectra, and UV-visifele spectra. The third-order nonlinear optical properties
were also investigated, and they exhibit good nonlinear absorption and self-defocusing performance with modulus of the hyperpolarizability
4.94 × 10−30 esu for I in a 6.35 × 10−4 mol dm−3 DMF solution. |
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