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| Crystal Structure of Adduct 2-Phenyl-imidazo [ 4,5-f ] 1,10-phenanthroline Methanol | |
| 引用本文： | 林惠文 朱文祥. Crystal Structure of Adduct 2-Phenyl-imidazo [ 4,5-f ] 1,10-phenanthroline Methanol[J]. 中国化学, 2003, 21(8): 1054-1058. DOI: 10.1002/cjoc.20030210816 |
| 作者姓名： | 林惠文 朱文祥 |
| 作者单位： | [1]DepartmentofChemistry,HainanNormalUniversity,Haikou,Hainan571158,China [2]DepartmentofChemistry,BeringNormalUniversity,Beijing100875,China |
| 基金项目： | theNaturalScienceFoundationofHainanProvinceofChina (No .2 0 0 0 4) |
| 摘 要： | The structure of the title adduct comprises a phenanthroline derivative 2-phenyl-imidazo[4,5-f]1,10-phenanthroline and a methanol.The composition of the crystalline adduct was characterized as C19H12N4.CH3OH.It belongs to orthorhombic system,space group Pna21 with a=1.3693(4)nm,b=2.2988(7)nm,c=0.51338(15)nm,V=1.6160(8)nm^3.Z=4,and final R1=0.0423.wR2=0.1012 .Crystal structure shows that all the 19 carbon atoms and 4 nitrogen atoms are coplanar.The bond length data indicated that a very extensive conjugation system was formed.This conjugation makes the compound being a potentially excellent energy transformer used for luminescent materials. |
| 关 键 词： | 晶体结构 晶体加合物 2-苯基-咪唑基[4 5-f]1 10-邻二氮杂菲 甲醇 铕配合物 发光材料 |
Crystal Structure of Adduct 2-Phenyl-imidazo[4,5-f] 1,10-phenanthroline Methanol |
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| Lin Hui‐Wen,Zhu Wen‐Xiang. Crystal Structure of Adduct 2-Phenyl-imidazo[4,5-f] 1,10-phenanthroline Methanol[J]. Chinese Journal of Chemistry, 2003, 21(8): 1054-1058. DOI: 10.1002/cjoc.20030210816 | |
| Authors: | Lin Hui‐Wen Zhu Wen‐Xiang |
| Abstract: | The structure of the title adduct comprises a phenanthroline derivative 2‐phenyl‐imidazo[4,5‐/]1,10‐phenanthroline and a methanol. The composition of the crystalline adduct was characterized as C19H12N4 CH3OH. It belongs to orthorhombic system, space group Pna21 with a = 1.3693(4) nm, b = 2.2988(7) nm, c =0.51338(15) nm, V = 1.6160(8) nm3, Z = 4, and final R1 = 0.0423, wR2 = 0.1012. Crystal structure shows that all the 19 carbon atoms and 4 nitrogen atoms are coplanar. The bond length data indicated that a very extensive conjugation system was formed. This conjugation makes the compound being a potentially excellent energy transformer used for luminescent materials. |
| Keywords: | phenanthroline derivative crystalline adduct crystal structure 2 phenyl imidazo[4 5 f ] 1 10 phenanthroline |
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