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NMR spectra of paramagnetic complexes of 1-vinylimidazole with iron group metals
Authors:V K Voronov  I A Ushakov  L V Baikalova
Institution:(1) Irkutsk State Technical University, 83 ul. Lermontova, 664074 Irkutsk, Russian Federation;(2) Irkutsk Institute of Chemistry of the Siberian Branch, Russian Academy of Sciences, 1 ul. Favorskogo, 664033 Irkutsk, Russian Federation
Abstract:The high-resolution 1H and 13C NMR spectra of 1-vinylimidazole complexes with iron group metals were recorded. The contact coupling in these systems was established in the 1H and 13C NMR spectra. The applicability of the NMR spectra transformed by long-range hyperfine coupling for elucidating the molecular structure of the ligand was shown. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1430–1433, June, 2005.
Keywords:NMR spectroscopy  paramagnetic complexes  hyperfine coupling  1-vinylimidazole
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