| STUDIES ON CHARGE TRANSFER POLYMERIZATION——POLYMERIZATION OF ACRYLONITRILE INITIATED WITH PHENYL HYDRAZINE AND ITS DERIVATIVES |
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| 引用本文： | 曹维孝,韩平,冯新德. STUDIES ON CHARGE TRANSFER POLYMERIZATION——POLYMERIZATION OF ACRYLONITRILE INITIATED WITH PHENYL HYDRAZINE AND ITS DERIVATIVES[J]. 高分子科学, 1983, 0(2): 189-195 |
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| 作者姓名： | 曹维孝 韩平 冯新德 |
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| 作者单位： | Department of Chemistry，Peking University，Department of Chemistry，Peking University，Department of Chemistry，Peking University |
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| 摘 要： | The photopolymerization of acrylonitrile (AN) initiated with phenyl hydrazine (PHZ) and its derivatives has been studied. The initiator exponent and monomer exponent were determined from the kinetic investigation to be 0.66th and 2.1th respectively and the overall activation energy was 33.4KJ/mol for the PHZ-AN system. Spectral analysis and other data indicate that a charge transfer complex between PHZ as a donor and AN as an aceeptor is formed. The initiation mechanism was proposed.
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| 收稿时间： | 1983-07-07 |
STUDIES ON CHARGE TRANSFER POLYMERIZATION——POLYMERIZATION OF ACRYLONITRILE INITIATED WITH PHENYL HYDRAZINE AND ITS DERIVATIVES |
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| CAO Weixiao,HAN Ping,FENG Xinde. STUDIES ON CHARGE TRANSFER POLYMERIZATION——POLYMERIZATION OF ACRYLONITRILE INITIATED WITH PHENYL HYDRAZINE AND ITS DERIVATIVES[J]. Chinese Journal of Polymer Science, 1983, 0(2): 189-195 |
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| Authors: | CAO Weixiao HAN Ping FENG Xinde |
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| Affiliation: | Department of Chemistry; Peking University |
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| Abstract: | The photopolymerization of acrylonitrile (AN) initiated with phenyl hydrazine (PHZ) and its derivatives has been studied. The initiator exponent and monomer exponent were determined from the kinetic investigation to be 0.66th and 2.1th respectively and the overall activation energy was 33.4KJ/mol for the PHZ-AN system. Spectral analysis and other data indicate that a charge transfer complex between PHZ as a donor and AN as an aceeptor is formed. The initiation mechanism was proposed. |
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