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| 叔丁基杯[6]芳烃的去叔丁基反应 | |
| 引用本文： | 武芸,曹端林,陈鑫,李永祥. 叔丁基杯[6]芳烃的去叔丁基反应[J]. 化学研究, 2007, 0(1): 46-48 |
| 作者姓名： | 武芸 曹端林 陈鑫 李永祥 |
| 作者单位： | 中北大学化工与环境学院,山西,太原,030051;中北大学化工与环境学院,山西,太原,030051;中北大学化工与环境学院,山西,太原,030051;中北大学化工与环境学院,山西,太原,030051 |
| 摘 要： | 报道了以对叔丁基杯[6]芳烃为原料,室温时,在三氯化铝催化下选择性脱去叔丁基的工艺.探讨了在合成去叔丁基杯[6]芳烃实验中催化剂用量对反应结果的影响,并对反应机理进行了讨论.结果表明,当n(AlCl3)∶n(p-tert-calix[6]arene)=8~9.5∶1时,分离得到了两种去叔丁基杯[6]芳烃:5-叔丁基-37,38,39,40,41,42-六羟基杯[6]芳烃和37,38,39,40,41,42-六羟基杯[6]芳烃,当n(AlCl3)∶n(p-tert-calix[6]arene)=10.5∶1时,得到37,38,39,40,41,42-六羟基杯[6]芳烃,产率90.8%. |
| 关 键 词： | 对叔丁基杯[6]芳烃 AlCl3 去叔丁基反应 |
| 文章编号： | 1008-1011（2007）01-0046-03 |
| 收稿时间： | 2006-11-03 |
| 修稿时间： | 2006-11-03 |
De-tert-butylation Reaction of Tert-butylcalix [6] arene |
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| WU Yun,CAO Duan-lin,CHEN Xin,LI Yong-xiang. De-tert-butylation Reaction of Tert-butylcalix [6] arene[J]. Chemical Research, 2007, 0(1): 46-48 | |
| Authors: | WU Yun CAO Duan-lin CHEN Xin LI Yong-xiang |
| Abstract: | The selective de-tert-butylation of p-tert-butyl calix[6]arene with AlCl3 at ambient temperature has been investigated.The effect of catalyst quantity was discussed on the basis of reaction mechanism.Mono-p-tert-butylc-alix[6]arene and de-tert-butyl calix[6]arene were obtained,when p-tert-butyl calix[6]arene was treated with 8~9.5 equivalents of AlCl3.De-tert-butyl calix[6]arene was exclusively obtained in yield of 90.8 % when 10.5 equivalents of AlCl3 was used at ambient temperature. |
| Keywords: | p-tert-butylcalix[6]arene AlCl3 de-tert-butylation reaction |
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