Addition of thiophenols to N-vinylpyrroles |
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| Authors: | I A Aliev A I Mikhaleva B R Gasanov |
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| Institution: | (1) Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, 664033 Irkutsk;(2) S. M. Kirov State University, 370073 Baku |
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| Abstract: | Thiophenols add to 1-vinyl-4,5,6,7-tetrahydroindole and 1-vinyl-2-phenylpyrrole in the presence of azobisisobutyronitrile to form 1-(2-arylthioethyl)pyrroles. The major products in the absence of initiator are the isomeric 1-(1-arylthioethyl)pyrrole  -adducts. NH-Pyrroles inhibit the radical process and form selectively the -adducts.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 750–752, June, 1990. |
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