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Synthesis, solid-state structures and metal ion complexation behavior of 2-picolyloxy lariat ethers |
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| Authors: | N Kent Dalley Jong Chan Lee Jing Wang |
| Institution: | a Department of Chemistry and Biochemistry, Brigham Young University, Provo, UT 84602, USA b Department of Molecular Microbiology and Biotechnology, George S. Wise Faculty of Life Sciences, Tel-Aviv University, 69978 Tel-Aviv, Israel c Department of Chemistry and Biochemistry, Texas Tech University, PO Box 41061, Lubbock, TX 79409, USA |
| Abstract: | Three new 2-picolyloxy lariat ether compounds are prepared and solid-state structures are determined for two of them. Complexation behavior for a series of lariat ethers with pyridyl-containing side arms toward alkali metal cations and Ag+ is assessed by two-phase metal picrate extraction from aqueous solutions into chloroform and in homogeneous solutions by isothermal titration calorimetry in methanol. |
| Keywords: | Lariat ethers Solid-state structures Picrate extraction Isothermal titration calorimetry |
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