Facile and chemo-selective synthesis of tertiary alkyl isothiocyanates from alcohols |
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Authors: | Hideyoshi Miyake Yuichi Nakao Mitsuru Sasaki |
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Affiliation: | Graduate School of Agricultural Science, Kobe University, Rokkodai, Nada-ku, Kobe 657-8501, Japan |
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Abstract: | When tert-alcohols were treated with (COOH)2 and NaSCN in the presence of iodine, tertiary alkyl isothiocyanates were obtained in good yield, whereas the corresponding thiocyanates were obtained in low yield in the absence of iodine. |
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