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Aza-Baylis-Hillman reaction of salicyl N-tosylimines with methyl vinyl ketone, ethyl vinyl ketone or phenyl vinyl ketone
Authors:Ming-Juan Qi
Affiliation:State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, 354 Fenglin Lu, Shanghai 200032, China
Abstract:Reactions of salicyl N-tosylimines with methyl vinyl ketone, ethyl vinyl ketone or phenyl vinyl ketone proceeded smoothly under mild conditions to give the corresponding chromanes or aza-Baylis-Hillman adducts in moderate to excellent yields in the presence of phosphine or nitrogen Lewis base.
Keywords:Salicyl N-tosylimines   Aza-Baylis-Hillman reaction   Chromanes   Michael addition
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