Aza-Baylis-Hillman reaction of salicyl N-tosylimines with methyl vinyl ketone, ethyl vinyl ketone or phenyl vinyl ketone |
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Authors: | Ming-Juan Qi |
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Affiliation: | State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, 354 Fenglin Lu, Shanghai 200032, China |
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Abstract: | Reactions of salicyl N-tosylimines with methyl vinyl ketone, ethyl vinyl ketone or phenyl vinyl ketone proceeded smoothly under mild conditions to give the corresponding chromanes or aza-Baylis-Hillman adducts in moderate to excellent yields in the presence of phosphine or nitrogen Lewis base. |
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Keywords: | Salicyl N-tosylimines Aza-Baylis-Hillman reaction Chromanes Michael addition |
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