Regioselective Reaction of N1-Benzyl-N2-(4-nitrophenyl)ethanediamide and Acetylenic Esters |
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Authors: | Issa Yavari Loghman Moradi Farough Nasiri and Hoorieh Djahaniani |
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Institution: | (1) Department of Chemistry, University of Mazandaran, 47415 Babolsar, Iran |
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Abstract: | The regioselective reaction of N1-benzyl-N2-(4-nitrophenyl)ethanediamide with dialkyl acetylenedicarboxylates or alkyl propiolates in the presence of triphenylphosphine
leads to dialkyl 4-benzylamino-1-(4-nitrophenyl)-5-oxo-2,5-dihydro-1H-pyrrole-2,3-dicarboxylates or alkyl 4-benzylamino-1-(4-nitrophenyl)-2-oxo-5-pyrrolidinecarboxylates in good yields. |
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