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Regioselective Reaction of N1-Benzyl-N2-(4-nitrophenyl)ethanediamide and Acetylenic Esters
Authors:Issa Yavari  Loghman Moradi  Farough Nasiri and Hoorieh Djahaniani
Institution:(1) Department of Chemistry, University of Mazandaran, 47415 Babolsar, Iran
Abstract:The regioselective reaction of N1-benzyl-N2-(4-nitrophenyl)ethanediamide with dialkyl acetylenedicarboxylates or alkyl propiolates in the presence of triphenylphosphine leads to dialkyl 4-benzylamino-1-(4-nitrophenyl)-5-oxo-2,5-dihydro-1H-pyrrole-2,3-dicarboxylates or alkyl 4-benzylamino-1-(4-nitrophenyl)-2-oxo-5-pyrrolidinecarboxylates in good yields.
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