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Assignment of the 5,6-Double-Bond Configuration in Iloprost and Isoiloprost from 13C-NMR Shifts Determined by 2D Methods
Authors:Kurt V Schenker  Wolfgang Von Philipsborn  C Anderson Evans  Werner Skuballa  Georg-Alexander Hoyer
Abstract:The configurations of the 5,6-double bond in the carbacyclins iloprost ( 3 ; (E)) and isoiloprost ( 4 ; (Z)) are based on a complete assignment of the 13C and 1H resonances determined by 1D and 2D 13C-NMR and 1H-NMR methods.
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