Umsetzungen von Metall- und Metalloidverbindungen mit mehrfunktionellen Molekülen. XV. Umsetzungen von N,O-Bis(trimethylsilyl)acylamiden mit Halogenboranen |
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Authors: | W Maringgele A Meller |
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Abstract: | Reactions of Metal and Metalloid Compounds with Polyfunctional Molecules. XV. Reaction of N, O-Bis(trimethylsilyl)acylamides with Halogenoboranes N, O-bis(trimethylsilyl) acylamides react with halogenodiorganylboranes to give monomeric iminoboranes, which are in equilibrium with the corresponding monomeric amidoboranes. In several cases we obtained dimeric amidoboranes, which partially are in equilibrium with the monomeric form. 1H, 11B and 19F n. m. r. spectra, mass spectra and characteristic i. r. group frequencies are reported. |
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