Galactose Oxidase models: 19F NMR as a powerful tool to study the solution chemistry of tripodal ligands in the presence of copper(II) |
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Authors: | Michel Fabien Hamman Sylvain Thomas Fabrice Philouze Christian Gautier-Luneau Isabelle Pierre Jean-Louis |
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Affiliation: | Laboratoire d'Etudes Dynamiques et Structurales de la Sélectivité, Equipe de Chimie Biomimétique, UMR CNRS 5616, ICMG FR CNRS 2607, Université Joseph Fourier, BP 53, 38041, Grenoble cedex 9, France. |
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Abstract: | In copper(ii) complexes of tripodal ligands, the protonation state of the phenol moiety, and its position (axial vs. equatorial), are easily assessed by (19)F NMR. |
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