Fluorooxoperoxo complexes of vanadium(V) |
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| Authors: | Peter Schwendt Daniela Joniaková |
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| Institution: | Department of Inorganic Chemistry, Comenius University, Mlynská dol., 842 15 Bratislava, Czechoslovakia |
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| Abstract: | Substances crystallizing under various conditions from the MVO3(MF, HF)H2O2H2O (M = NH4, K) systems have been characterized by elemental analysis, infrared and Raman spectra and X-ray powder patterns. Besides the known M2VO(O2)2F] complexes, complexes of two new types have been obtained: M3HV2O2(O2)3F4·2H2O and (NH4)3V2O2(O2)4F]·nH2O (n≈2). Vibrational spectra of new complexes are consistent with the presence of dimeric anions containing V(μ2O2)V and VFV bridges, respectively. |
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| Keywords: | Author to whom correspondence should be addressed |
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