| D-葡萄糖与氯化稀土配合物的合成及红外光谱研究 |
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| 引用本文： | 杨延民,翁诗甫,吴谨光,徐光宪.D-葡萄糖与氯化稀土配合物的合成及红外光谱研究[J].高等学校化学学报,1994,15(5):646. |
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| 作者姓名： | 杨延民 翁诗甫 吴谨光 徐光宪 |
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| 作者单位： | 北京大学化学系, 北京, 100871 |
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| 摘 要： | 以非水溶剂为介质合成了D-葡萄糖、氯化稀土、吡啶的混配多元配合物,并进行了元素分析和红外光谱测定。研究结果表明,D-葡萄糖和溶剂吡啶同时参与了配位,该配合物的组成为:Ln(C6H12O6)(C5H5N)Cl3(Ln=La,Ce,Pr,Nd,Sm等).本文还对配合物的可能结构进行了讨论。
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| 关 键 词： | D-葡萄糖 糖与氯化稀土配合物 傅里叶变换红外光谱 |
| 收稿时间： | 1993-05-12 |
Synthesis and FTIR Spectroscopy Study of the Rare Earth Complexes with D-Glucose |
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| YANG Yan-Min, WENG Shi-Fu, WU Jin-Guang, XU Guang-Xian.Synthesis and FTIR Spectroscopy Study of the Rare Earth Complexes with D-Glucose[J].Chemical Research In Chinese Universities,1994,15(5):646. |
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| Authors: | YANG Yan-Min WENG Shi-Fu WU Jin-Guang XU Guang-Xian |
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| Institution: | Department of Chemistry, Peking University, Beijing, 100871 |
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| Abstract: | Rare earth complexes with D-glucose were successfully prepared in pyridine and characterized by elementary analysis and FTIRmeasurements. The experimental results indicate that each rare earth ion is coordinated to two glucose molecules and one pyridine molecule. The composition of rare earth complexes with D-glucose is Ln(C6H12O6)·(C5H5N)Cl3. The potential structure of this compound is discussed. |
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| Keywords: | D-glucose Rare earth chloride complexes with D-glucose FTIR spectra |
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