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Synthesis and characterization of isomanolonitrile dithiolato palladium complexes. Crystal structure of (PPh3)2Pd(S2C4N2) and (Et4N)2WS4Pd(S2C4N2) |
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| Authors: | Deliang Long Hegen Zheng Xinquan Xin Genta Sakane Takashi Shinahara |
| Institution: | a State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing, 210093, P.R. China b Department of Chemistry, Okayama University of Science, 1-1 Ridai-cho, Okayama 700, Japan |
| Abstract: | A series of isomalononitrile dithiolato palladium complexes, (PPh3)2Pd(1-mnt) (1), P(OPh)3]2Pd(i-mnt) (2), (PPh3)(py)Pd(i-mnt)·CH3CN (4), (Et4N)2Pd(i-mnt)2 (4) and (Ph4As)2Pd(i-mnt)2 (5) were synthesized and characterized by elemental analysis and IR spectroscopy. The reaction between (Et4N)2Pd(i-mnt)2 (4) and (Et4N)2WS4 gave a mixed metal cluster (Et4N)2WS4Pd(i-mnt) (6). The crystallographically determined structures of 1 and 6 are reported. |
| Keywords: | synthesis crystal structure palladium dithiolate coordination compounds substitution reaction |
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