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Proton-conducting membranes based on multicomponent copolymers
Authors:S. S. Ivanchev  O. N. Primachenko  V. N. Pavlyuchenko  S. Ya. Khaikin  V. A. Trunov
Affiliation:(1) St. Petersburg Branch, Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, St. Petersburg, Russia;(2) Konstantinov Institute for Nuclear Physics, Russian Academy of Sciences, Gatchina, Leningrad oblast, Russia
Abstract:Preparation of proton-conducting polymeric composites via copolymerization of multicomponent monomeric systems using the interpenetrating polymer network preparation procedure is studied. The products are characterized by the protonic conductivity, water-retaining capacity, and mechanical properties. The approach used allows fabrication of membranes with a reasonable protonic conductivity over the temperature range 20–90°C. A possibility of modification of the proton-conducting materials with small additions of hydrolyzable organosilicon comonomers is analyzed. The structure of the resulting systems is examined by small-angle neutron scattering.
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