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Thermal Behavior,Nonisothermal Decomposition Reaction Kinetics of Mixed Ester Double-base Gun Propellants
Authors:YI Jian-hua  ZHAO Feng-qi  XU Si-yu  GAO Hong-xu  HU Rong-zu
Affiliation:Xi'an Modern Chemistry Research Institute, Xi'an 710065, P. R. China
Abstract:
The thermal decomposition behavior and nonisothermal reaction kinetics of the double-base gun propellants containing the mixed ester of triethyleneglycol dinitrate(TEGDN) and nitroglycerin(NG) were investigated by thermogravimetry(TG) and differential thermogravimetry(DTG), and differential scanning calorimetry(DSC) under the high-pressure dynamic ambience. The results show that the thermal decomposition processes of the mixed nitric ester gun propellants have two mass-loss stages. Nitric ester evaporates a...
Keywords:Mixed nitric ester gun propellant  Triethyleneglycol dinitrate  Thermal behaviors  Nonisothermal decomposition reaction kinetics
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