| [Na_4(H_2O)_7][Fe(OH)_6Mo_6O_(18)]: a new [12] metallacrown-6 structure with an octahedrally coordinated iron at the center |
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| 作者姓名： | 吴传德 林祥 余荣民 杨文斌 卢灿忠 庄鸿辉 |
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| 作者单位： | WU Chuande LIN Xiang YU RongminYANG Wenbin LU Canzhong ZHUANG HonghuiState Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences，Fuzhou 350002，China |
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| 基金项目： | the State Key Lab. of Structural Chemistry, the Chinese Academy of Sciences and the State Personnel Ministry. |
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| 摘 要： | The reaction of an aqueous solution of sodium molybdate with iron powder at low pH (-0.184) gives rise to the formation of a six-member Mo ring-shape cluster with an Fe (II) encapsulated at the center, Na4(H2O)7]Fe(OH)6Mo6O18](1), which is further linked to a remarkable three-dimensional network via sodium ions.
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[Na_4(H_2O)_7][Fe(OH)_6Mo_6O_(18)]: a new [12] metallacrown-6 structure with an octahedrally coordinated iron at the center |
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| WU Chuande LIN Xiang YU RongminYANG Wenbin LU Canzhong ZHUANG HonghuiState Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou ,China.[Na_4(H_2O)_7][Fe(OH)_6Mo_6O_(18)]: a new [12] metallacrown-6 structure with an octahedrally coordinated iron at the center[J].Science in China(Chemistry),2001(1). |
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| Authors: | WU Chuande LIN Xiang YU RongminYANG Wenbin LU Canzhong ZHUANG HonghuiState Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou China |
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| Institution: | WU Chuande LIN Xiang YU RongminYANG Wenbin LU Canzhong ZHUANG HonghuiState Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002,China |
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| Abstract: | The reaction of an aqueous solution of sodium molybdate with iron powder at low pH (-0.184) gives rise to the formation of a six-member Mo ring-shape cluster with an Fe (II) encapsulated at the center, Na4(H2O)7]Fe(OH)6Mo6O18](1), which is further linked to a remarkable three-dimensional network via sodium ions. |
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| Keywords: | [12] metallacrown-6 structure ring-shaped cluster three-dimensional network ESR |
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