Mechanistic implications from the substitution reactions with methyl fluoride of photochemically produced hot tritium atoms期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Mechanistic implications from the substitution reactions with methyl fluoride of photochemically produced hot tritium atoms

Authors:	C.C. Chou D.D. Wilkey F.S. Rowland

Affiliation:	Department of Chemistry, University of California, Irvine, California 92664, USA

Abstract:	The reactions with CH₃F of photochemically produced tritium atoms from TBr have been studied at various wavelengths. The energy threshold is lower and the relative yield higher for F replacement than for H replacement in CH₃F. These near-threshold substitution reactions are consistent with an inversion mechanism.

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