Spectroscopic evidence for a delocalized excited state in the magnus salts |
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| Authors: | Basil G. Anex Stephen I. Foster Anthony F. Fucaloro |
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| Affiliation: | Department of Chemistry, New Mexico State University, Las Cruces, New Mexico 88001, USA;Department of Chemistry, Louisiana State University, New Orleans, Louisiana 70122, USA |
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| Abstract: | ![]()
The polarized single-crystal spectra of the Magnus salts [Pt(NH3)4][PtCl4], [Pd(NH3)4] [PtCl4], [Pt(NH3)4] [PdCl4], and [Pd(NH3)4][PdCl4] have been obtained in the quartz ultraviolet and visible regions. These results provide strong evidence for a delocalized excited state being associated with the intense ultraviolet transition found in the spectra of the Magnus salts. One thus has available an important new criterion for the evaluation of the theoretical treatments of these systems. |
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| Keywords: | Correspondence should be addressed to this author at the Louisiana State University address indicated above. |
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