Transient ion pairs from OH-radical reactions: Pulse radiolysis of aqueous alkyl iodide solutions |
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| Authors: | U. Brühlmann H. Büchler F. Marchetti R.E. Bühler |
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| Affiliation: | Laboratory for Physical Chemistry, Swiss Federal Institute of Technology, CH-8006 Zurich, Switzerland |
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| Abstract: | Pulse radiolysis studies of aqueous alkyl iodide solutions reveal the existence of the transient ion pair (HOI?.R+)aq. This species is formed by OH-radical reaction with the alkyl iodide followed by a rapid solvent-assisted rearrangement from the outer to the inner charge-transfer complex. |
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