Metallorganische lewissäuren : XX. Reaktionen von (π-C5H5)(CO)2LM-X (L = CO, PR3; M = Mo, W; X = BF4, PF6, AsF6, SbF6) mit Schwefel-haltigen liganden |
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| Authors: | Günter Urban Karlheinz Sünkel Wolfgang Beck |
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| Institution: | Institut für Anorganische Chemie der Universität München, Meiserstr. 1, 8000 München 2 B.R.D. |
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| Abstract: | The compounds (π-C5H5)(CO)2LM-X (L = CO, PR3; M = Mo, W; X = BF4, PF6, AsF6, SbF6) react with H2S, p-MeC6H4SH, Ph2S and Ph2SO(L′) to give ionic complexes (π-C5H5)(CO)2LML′]+ X−. Also sulfur-bridged complexes, (π-C5H5)(CO)3W---SH---W(CO)3(π-C5H5)]+ AsF6− and (π-C5H5)(CO)3M-μ-S2C=NCH2Ph-M(CO)3(π-C5H5)], have been obtained. Reactions with SO2 and CS2 have been examined. |
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