| 合成光学活性菊酸酯的方法 |
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| 引用本文： | 李争宁,陈惠麟. 合成光学活性菊酸酯的方法[J]. 合成化学, 2000, 8(6): 469-471 |
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| 作者姓名： | 李争宁 陈惠麟 |
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| 作者单位： | 中国科学院大连化学物理研究所,大连,116023;中国科学院大连化学物理研究所,大连,116023 |
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| 摘 要： | Ｌ－孟醇与过量外消旋菊酰氯反应表现出非对映异构体选择性,得到了光学活性菊酸的Ｌ－孟醇酯。由外消旋菊酸的Ｌ－孟醇酯经异构化反应也得到了光学活性菊酸的Ｌ－孟醇酯。
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| 关 键 词： | 菊酸 孟醇 酯 光学活性 手性识别 异构化 |
Novel Synthesis of Optically Active Chrysanthemic Acid Ester |
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| Abstract. Novel Synthesis of Optically Active Chrysanthemic Acid Ester[J]. Chinese Journal of Synthetic Chemistry, 2000, 8(6): 469-471 |
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| Authors: | Abstract |
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| Abstract: | L-Menthanol ester of chiral chrysanthemic acid was obtained via stereoselective esterification of the racemic acid, and the result was analyzed by MOPAC. Promoted by the above phenomenon, we obtained L-menthol ester of chiral chrysanthemic acid via the isomerization of L-menthol ester of racemic chrysanthemic acid. |
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| Keywords: | Menthanol Isomerization Chrysanthemic acid Steroselectivity Esterification |
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